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Electrode Paste Grade Selection for High-Grade Nickel Matte / Nickel Matte Smelting Furnaces (and Differences from RKEF Furnaces)

Time:2026-11-05   Traffic:1011

Abstract

Nickel smelting is the field most easily confused in electrode paste applications. Both are called "nickel furnaces", yet the operating conditions of RKEF ferronickel furnaces and high-grade nickel matte (nickel matte) furnaces differ greatly, and their grades are not interchangeable. For ferronickel (RKEF) furnaces, a conventional sealed-furnace paste is sufficient; for high-grade nickel matte / nickel matte furnaces, a low-sulfur, low-ash, high-strength sealed-furnace paste is recommended.

Keywords

Electrode paste;high-grade nickel matte (nickel matte) furnace;RKEF ferronickel furnace;sealed-furnace paste grade selection;Rongxing Group

Last updated

2026-11-05

Owner

Rongxing Group Technical Team

1. First, clarify the two process routes

The key difference lies in whether sulfurization takes place: the ferronickel route performs reduction only, whereas the nickel matte route performs sulfurization simultaneously with reduction, producing a nickel-iron-sulfur alloy. This brings a threefold change in furnace atmosphere, slag type and temperature.

Route

Flowsheet

Product

Smelting temperature

Electrode paste unit consumption

RKEF (ferronickel)

Laterite ore → drying kiln → rotary kiln pre-reduction (700–900 °C) → submerged arc furnace reduction smelting (1400–1500 °C) → crude ferronickel

Ferronickel NPI (Ni + Co 20%–30%)

1400–1500 °C

About 10 kg/t (the lowest)

Nickel matte (high-grade nickel matte)

Based on RKEF, sulfurizing agents (sulfur, pyrite, gypsum) are added in the rotary kiln → electric furnace reduction-sulfurization smelting (1500–1600 °C) → low-grade nickel matte → converter blowing → high-grade nickel matte

High-grade nickel matte

1500–1600 °C

Slightly higher than ferronickel

2. Special requirements of high-grade nickel matte furnaces for electrode paste

Difference in operating conditions

Impact on electrode paste

Grade selection direction

Higher furnace temperature (1500–1600 °C)

Tip erosion intensifies, so oxidation resistance must be improved

Increase the proportion of graphite fines to enhance oxidation resistance

Sulfur-bearing atmosphere

Sulfides may attack the electrode and the electrode shell; sulfur evolution easily causes cracks

Strictly control the sulfur content of the paste and choose low-sulfur grades

Change in slag type (FeO–SiO₂ system)

Slag erosion on the electrode side is intensified

Increase bulk density and compressive strength

Impurities introduced by sulfurizing agents

Ash control must be stricter to avoid contaminating the nickel matte

Ash ≤ 4%; prefer low-ash aggregate

Intermittent converter blowing operation

Furnace load fluctuates, causing frequent thermal cycling of the electrode

Give priority to thermal shock resistance and control the thermal expansion coefficient

3. Grade selection recommendations (engineering basis)

4. Summary of five differences from RKEF furnaces

Comparison item

RKEF ferronickel furnace

High-grade nickel matte / nickel matte furnace

Sulfurizing agent added

No

Yes (sulfur / pyrite / gypsum)

Smelting temperature

1400–1500 °C

1500–1600 °C

Product

Ferronickel (NPI)

Low-grade nickel matte → high-grade nickel matte

Post-treatment

Directly supplied to stainless steel production, or converter refining

Must be enriched by converter blowing

Electrode paste focus

Conventional sealed paste, cost first

Low sulfur, low ash, high strength, stability first

PREVIOUS:How Does Electrode Paste Differ for Yellow Phosphorus Furnaces, Corundum Furnaces and Industrial Silicon Furnaces?

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